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bdshare-button-style0-24" data-bd-bind="1553828600291"> <a href="#" class="bds_tsina" data-cmd="tsina" title="分享到新浪微博"></a> <a href="#" class="bds_weixin" data-cmd="weixin" title="分享到微信"></a> <a href="#" class="bds_sqq" data-cmd="sqq" title="分享到QQ好友"></a> </div> <script>window._bd_share_config={"common":{"bdSnsKey":{},"bdText":"","bdMini":"2","bdMiniList":false,"bdPic":"","bdStyle":"0","bdSize":"24"},"share":{}};with(document)0[(getElementsByTagName('head')[0]||body).appendChild(createElement('script')).src='http://bdimg.share.baidu.com/static/api/js/share.js?v=89860593.js?cdnversion='+~(-new Date()/36e5)];</script> </div> <script src="/jslib/paging/contentPaging.js"></script>  <div id="kwmiu0s" class="articleTitle">從硫酸鋁到氟離子，探索無(wú)堿速凝劑的進(jìn)階之路</div> <div id="s0yusse" class="articleTime"> <div id="4ascwg0" class="center"> <div id="scyomg0" class="articleTimeTxt fl"><em class="em1">管理員</em><em class="em2">2024-07-15</em> <em class="em3">12</em> </div> </div> </div>   <div id="uy0ay0o" class="h10"></div> <div id="ucmieec" class="articleBox">     <div id="wa0eyee" class="wow fadeIn" id="articleContent">  <h1 align="center" style="text-align:left;margin-left:0pt;text-indent:0pt;"> <span style="font-size:16px;line-height:1.5;"><strong>引言：</strong></span> </h1> <p> <span style="font-size:16px;line-height:1.5;"><strong><br /> </strong></span> </p> <h1 align="center" style="text-align:left;margin-left:0pt;text-indent:0pt;"> <span style="font-size:16px;line-height:1.5;"><strong>速凝劑是能使混凝土迅速凝結硬化的外加劑，是噴射混凝土施工中重要的材料，其主要功能是加速?lài)娚浠炷恋哪Y硬化速度，減少回彈損失，防止噴射混凝土因重力引起脫落，加大一次噴射厚度和縮短噴射層間的間隔時(shí)間。</strong></span><strong style="text-indent:0pt;font-size:14px;"><span style="font-size:16px;">近年</span></strong><strong style="text-indent:0pt;font-size:16px;">來(lái)，以硫酸鋁型液體速凝劑為代表的無(wú)堿速凝劑，憑借其優(yōu)秀的長(cháng)期強度保有率、安全環(huán)保和優(yōu)良耐久性等優(yōu)點(diǎn)，逐步取代了有堿速凝劑，越來(lái)越多地被應用在鐵路、隧道、水利、交通和采礦等工程中。</strong> </h1> <p> <span style="font-size:16px;line-height:2.5;"><br /> </span> </p> <p class="p" style="margin-left:0.0000pt;text-indent:0.0000pt;"> <span style="font-size:24px;text-indent:0pt;line-height:1.5;">? 無(wú)堿速凝劑中的硫酸鋁</span> </p> <p class="p" style="margin-left:0.0000pt;text-indent:0.0000pt;"> <span style="font-size:16px;line-height:2.5;"><br /> </span> </p> <p class="p" style="margin-left:0.0000pt;text-indent:0.0000pt;"> <span style="font-size:16px;line-height:1.5;">硫酸鋁中的鋁離子和硫酸根離子進(jìn)入水泥后可促進(jìn)鈣礬石生成，使水泥快速凝結，然而，與傳統的以鋁酸鈉為核心的有堿速凝劑相比，以硫酸鋁為主要組分的無(wú)堿速凝劑可溶性鋁含量不足，為滿(mǎn)足實(shí)際施工需求，必須提高其摻入比例。但這樣做無(wú)疑會(huì )增加使用成本，影響速凝劑產(chǎn)品的市場(chǎng)競爭力。因此，提升無(wú)堿速凝劑中鋁離子的濃度成為了亟需解決的問(wèn)題。然而，高濃度的硫酸鋁溶液容易析晶，且鋁離子在水中極易發(fā)生水解</span><span style="font-size:16px;line-height:1.5;">-聚合-沉淀的反應，這會(huì )使溶液變成不可逆的凝膠態(tài)，嚴重損害速凝劑產(chǎn)品的穩定性。針對這一難題，有一個(gè)有效的解決方法：在體系中加入含有絡(luò )合基團的物質(zhì)，提高硫酸鋁的溶解度，從而增加鋁離子在溶液中的穩定性。</span> </p> <p class="p" style="margin-left:0.0000pt;text-indent:0.0000pt;"> <span style="font-size:16px;line-height:2.5;"><br /> </span> </p> <p class="p" style="margin-left:0.0000pt;text-indent:0.0000pt;"> <span style="font-size:24px;line-height:1.5;">? 無(wú)堿速凝劑中的氟</span> </p> <p class="p" style="margin-left:0.0000pt;text-indent:0.0000pt;"> <span style="font-size:16px;line-height:2.5;"><br /> </span> </p> <p class="p" style="margin-left:0.0000pt;text-indent:0.0000pt;"> <span style="font-size:16px;line-height:1.5;">氟離子具有超強的絡(luò )合鋁離子的能力，可以顯著(zhù)提高溶液中鋁離子的濃度，改善硫酸鋁的穩定性；此外，氟鋁絡(luò )合離子的反應活性高于鋁離子，可以在較低的摻量下達到良好的促凝效果。因此，含氟產(chǎn)品被引入了無(wú)堿速凝劑的生產(chǎn)中。早幾年廣泛使用的含氟原料是氫氟酸，但由于氫氟酸在提高早期強度方面效果不佳，且因腐蝕性強，在運輸、存儲、生產(chǎn)等方面都有嚴格要求，后來(lái)逐漸被腐蝕性和使用成本更低的氟硅酸取代。近兩年，施工要求逐步增高，速凝劑市場(chǎng)競爭也日漸激烈，為了加強速凝劑產(chǎn)品市場(chǎng)競爭力，各種新的原料不斷被發(fā)掘，冰晶石、氟硅酸鈉等含氟產(chǎn)品被大量應用于無(wú)堿速凝劑生產(chǎn)，開(kāi)發(fā)出了多種速凝劑新產(chǎn)品。</span> </p> <p class="p" style="margin-left:0.0000pt;text-indent:0.0000pt;"> <span style="font-size:16px;line-height:2.5;"><br /> </span> </p> <p class="p" style="margin-left:0.0000pt;text-indent:0.0000pt;"> <span style="font-size:24px;line-height:1.5;">?無(wú)堿速凝劑發(fā)展展望</span> </p> <p class="p" style="margin-left:0.0000pt;text-indent:0.0000pt;"> <span style="font-size:16px;line-height:2.5;"><br /> </span> </p> <p class="p" style="margin-left:0.0000pt;text-indent:0.0000pt;"> <span style="font-size:16px;line-height:1.5;">速凝劑，作為混凝土外加劑的重要成員，其發(fā)展歷程見(jiàn)證了建筑行業(yè)對材料性能與環(huán)保要求的雙重提升。從傳統的高堿速凝劑到低堿、直至現今的無(wú)堿速凝劑，每一次變革都緊密?chē)@高效施工與綠色環(huán)保兩大核心展開(kāi)。云南氟業(yè)，作為行業(yè)內的領(lǐng)軍企業(yè)，早在</span><span style="font-size:16px;line-height:1.5;">2019年便敏銳捕捉到這一行業(yè)趨勢，并積極與上海同濟大學(xué)孫振平教授團隊等權威機構建立戰略合作關(guān)系。通過(guò)深化產(chǎn)學(xué)研合作，云南氟業(yè)在無(wú)堿速凝劑的研發(fā)與應用上取得了顯著(zhù)成果。經(jīng)過(guò)多年的研究，其速溶粉第3代產(chǎn)品，憑借優(yōu)異的混合均勻性、穩定性和廣泛的適應性，為施工過(guò)程提供了穩定且高效的解決方案。</span> </p> <p class="p" style="margin-left:0.0000pt;text-indent:0.0000pt;"> <span style="font-size:16px;line-height:1.5;"><br /> </span> </p> <p class="p" style="margin-left:0.0000pt;text-indent:0.0000pt;"> <span style="font-size:16px;line-height:1.5;">在未來(lái)，云南氟業(yè)將繼續秉承</span><span style="font-size:16px;line-height:1.5;">“高效施工、綠色環(huán)?！钡睦砟?，與合作伙伴共同探索速凝劑領(lǐng)域的新技術(shù)、新應用。通過(guò)不斷創(chuàng )新與優(yōu)化，云南氟業(yè)有望為速凝劑行業(yè)樹(shù)立新的標桿，為推動(dòng)建筑行業(yè)的可持續發(fā)展做出積極貢獻。如果是您正被速凝劑的包裝、運輸和存儲問(wèn)題困擾，結合性能方面還想優(yōu)中選優(yōu)的話(huà)，希望我們的第3代無(wú)堿速凝劑（速溶粉）能成為您的工程首選。</span> </p> <p class="p" style="margin-left:0.0000pt;text-indent:0.0000pt;"> <span style="font-size:16px;line-height:2.5;"><br /> </span> </p> <p class="p" align="center" style="margin-left:0.0000pt;text-indent:0.0000pt;text-align:center;"> <span style="font-size:24px;line-height:1.5;">?聯(lián)系方式與關(guān)注</span> </p> <p class="p" align="center" style="margin-left:0.0000pt;text-indent:0.0000pt;text-align:center;"> <span style="font-size:16px;line-height:1.5;">王琳：</span><span style="font-size:16px;line-height:1.5;">18987148746</span> </p> <p class="p" align="center" style="margin-left:0.0000pt;text-indent:0.0000pt;text-align:center;"> 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